Operation performance of PEM electrolyzer in dual-mode operation for hydrogen production and hot standby with integrated ammonia synthesis waste heat storage and utilization

裴长运; 孙名家; 王桂楠; 殷诗奇; 王露; 宋玮; 彭莘; 于吉庆; 杜逸云; 郭铁柱; 张汉飞

doi:10.19666/j.rlfd.202411252

English

您当前的位置：

首页 >

文章列表页 >

Operation performance of PEM electrolyzer in dual-mode operation for hydrogen production and hot standby with integrated ammonia synthesis waste heat storage and utilization

Thermal Power Generation Vol. 54, Issue 8, Pages: 84-94(2025)

更新时间：2026-08-11

- Operation performance of PEM electrolyzer in dual-mode operation for hydrogen production and hot standby with integrated ammonia synthesis waste heat storage and utilization
- 作者机构：
  
  1. 国核电力规划设计研究院有限公司
  2. 华北电力大学能源动力与机械工程学院
  3. 吉林电力股份有限公司
  4. 大安吉电绿氢能源有限公司
- 作者简介：
- 基金信息：
- DOI：10.19666/j.rlfd.202411252
  CLC： TQ113.2;TQ116.2
- Published：2025
- 稿件说明：
移动端阅览
[1]裴长运,孙名家,王桂楠,等.集成合成氨余热储存利用质子交换膜电解槽制氢/热备双模式运行性能[J],2025,54(08):84-94.
[1]裴长运,孙名家,王桂楠,等.集成合成氨余热储存利用质子交换膜电解槽制氢/热备双模式运行性能[J],2025,54(08):84-94. DOI： 10.19666/j.rlfd.202411252.

DOI：10.19666/j.rlfd.202411252.

摘要

绿电制氢合成氨是大规模消纳风光可再生电能并解决绿色燃料化学品短缺问题的有效方案。提出了一种集成合成氨余热储存利用的风光驱动质子交换膜电解槽制氢/热备双模式运行系统，避免电解槽频繁启停并合理解决合成氨工艺余热浪费问题。结果表明：双模式运行系统可大幅降低电解槽启动时间，951 kW电解槽25℃冷启动耗时512 s，从热备模式47.5℃热启动仅需274 s；系统在热备模式下仅给水泵耗电，单位制氢容量耗电功率为0.49 kW；双罐储热子系统配置10.8 t Dowtherm-G导热油，在蓄热状态以3 kg/s的流量吸收合成氨装置余热气体，可使热罐1.00 h内储满，在放热状态以0.64 kg/s的流量加热电解槽入口给水，可使电解槽热备状态持续运行4.68 h。此外，通过制氢/热备双模式运行产生的收益超出储热子系统投资，具有良好的经济性。

Abstract

Ammonia synthesize through hydrogen produced by green electricity offers an effective solution to the widespread abandonment of wind and solar resources and the shortage of green fuel chemicals. A wind-solar-driven proton exchange membrane(PEM) electrolyzer system in dual-mode operation for hydrogen production and hot standby with integrated ammonia synthesis waste heat storage is proposed

addressing issues of frequent start-stop cycles under fluctuating wind-solar outputs and waste heat recovery in ammonia synthesis processes. The results indicate that

the PEM electrolyzer dual-mode operating system

integrated with ammonia synthesis waste heat storage

can significantly shorten the startup time of the electrolyzer. The startup time at 25 ℃ is 512 seconds

while the hot startup from the standby mode at 47.5 ℃ requires only 274 seconds. Under hot standby mode

the system consumes electricity solely from feedwater pumps

achieving a specific hydrogen production power consumption of only 0.49 kW. The dual-tank thermal storage subsystem is configured with 10.8 tons of Dowtherm-G heat transfer oil. In heat storage mode

it absorbs waste heat gas from the ammonia synthesis unit at a flow rate of 3 kg/s

allowing the thermal tank to reach full capacity within 1 hour. In heat release mode

it heats the electrolyzer inlet water at a flow rate of 0.64 kg/s

enabling the electrolyzer to sustain standby operation for 4.68 hours. Furthermore

the new system is expected to generate long-term benefits that consistently exceed costs

ensuring sustained economic viability.

关键词

Keywords

references

1445号[A].(2021-10-21)[2024-11-28].National Development and Reform Commission, National Energy Administration, Ministry of Finance, Ministry of Natural Resources, Ministry of Ecological Environment,Ministry of Housing and Urban-Rural Development,Ministry of Agriculture and Rural Affairs, China Meteorological Administration, National Forestry and Grassland Administration. Notice on the 14th Five-Year Plan for the Development of Renewable Energy:FGNY

No.1445[A].(2021-10-21)[2024-11-28].

王宇轩,江路毅,范雪飞.基于氢储能的直流微电网系统功率分配策略研究[J].热力发电, 2023, 52(11):105-114.WANG Yuxuan, JIANG Luyi, FAN Xuefei. Research on power distribution strategy of DC microgrid system based on hydrogen energy storage[J]. Thermal Power Generation, 2023, 52(11):105-114.

吉旭,周步祥,贺革,等.大规模可再生能源电解水制氢合成氨关键技术与应用研究进展[J].工程科学与技术, 2022, 54(5):1-11.JI Xu, ZHOU Buxiang, HE Ge, et al. Research review of the key technology and application of large-scale water electrolysis powered by renewable energy to hydrogen and ammonia production[J]. Engineering Science and Technology, 2022, 54(5):1-11.

徐也茗,郑传明,张韫宏.氨能源作为清洁能源的应用前景[J].化学通报, 2019, 82(3):214-220.XU Yeming, ZHENG Chuanming, ZHANG Yunhong.Application prospect of ammonia energy as clean energy[J]. Chemical Bulletin, 2019, 82(3):214-220.

段向阳.可再生能源电解水制氢技术研究进展[J].节能, 2024, 43(10):122-125.DUAN Xiangyang. Research progress on hydrogen production from water electrolysis using renewable energy[J]. Energy Conservation, 2024, 43(10):122-125.

SHARIFZADEH M, COOPER N, VAN’T NOORDENDE H, et al. Operational strategies and integrated design for producing green hydrogen from wind electricity[J]. International Journal of Hydrogen Energy, 2024, 64:650-675.

高波,王佳琪,刘志亮,等.海上风电制氢系统建模及热力学与经济学分析[J].化工学报, 2025, 76(3):1207-1220.GAO Bo, WANG Jiaqi, LIU Zhiliang, et al. Modeling and thermodynamic and economic analysis of offshore wind power-based hydrogen production systems[J]. Chemical Engineering Journal, 2025, 76(3):1207-1220.

HOLMES-GENTLE I, TEMBHURNE S, SUTER C, et al.Dynamic system modeling of thermally-integrated concentrated PV-electrolysis[J]. International Journal of Hydrogen Energy, 2021, 46(18):10666-10681.

张文韬,周家辉,徐钢,等.计及电解槽自保温的风光制氢系统研究[J].现代化工, 2024, 44(4):204-208.ZHANG Wentao, ZHOU Jiahui, XU Gang, et al. Research on wind-solar energies-driven hydrogen production system considering self-insulation at electrolytic cell[J].Modern Chemical Industry, 2024, 44(4):204-208.

SIECKER J, KUSAKANA K, NUMBI B P. Optimal heat recovery during polymer electrolyte membrane electrolysis[J]. International Journal of Hydrogen Energy,2022, 47(76):32692-32706.

PENG X, DENG Z, ZHAO X, et al. Experimental and analytical study of a proton exchange membrane electrolyser integrated with thermal energy storage for performance enhancement[J]. International Journal of Photoenergy, 2022, 2022(1):7543121.

ANWAR M, MEHDIZADEH A, KARIMI N. Waste heat recovery from a green ammonia production plant by Kalina and vapour absorption refrigeration cycles:a comparative energy, exergy, environmental and economic analysis[J]. Sustainable Energy Technologies and Assessments, 2024, 69:103916.

ZHANG T, SHE X, NIE B, et al. Integration of liquid air energy storage with ammonia synthesis process for resource efficiency and cost-effectiveness[J]. Journal of Energy Storage, 2024, 97:112637.

YANG S, WU H, SONG J, et al. Two-stage robust optimization scheduling for integrated energy systems considering ammonia energy and waste heat utilization[J].Energy Conversion and Management, 2024, 319:118922.

林志强.合成氨生产中蒸汽余热综合利用的技术研究[J].化肥设计, 2024, 62(5):49-51.LIN Zhiqiang. Technical research on comprehensive utilization of steam waste heat in ammonia production[J].Chemical Fertilizer Design, 2024, 62(5):49-51.

SLEITI A K, AL-AMMARI W A, MUSHARAVATI F.Novel integrated system for power, hydrogen, and ammonia production using direct oxy-combustion s CO2power cycle with automatic CO2 capture, water electrolyzer, and Haber-Bosch process[J]. Energy, 2024,307:132554.

ZHANG H, WANG L, VAN HERLE J, et al. Technoeconomic comparison of green ammonia production processes[J]. Applied Energy, 2020, 259:114135.

ZHANG Y, WANG Z, DU Z, et al. Techno-economic analysis of solar hydrogen production via PV power/concentrated solar heat driven solid oxide electrolysis with electrical/thermal energy storage[J].Journal of Energy Storage, 2023, 72:107986.

SU C, CHEN Z, WU Z, et al. Experimental and numerical study of thermal coupling on catalyst-coated membrane for proton exchange membrane water electrolyzer[J].Applied Energy, 2024, 357:122442.

KOCALMIS BILHAN A. Integrated solar-based PEMWEs for green electricity production[J]. International Journal of Hydrogen Energy, 2024, 75:415-427.

LIU L, ZHAI R, HU Y. Multi-objective optimization with advanced exergy analysis of a wind-solar-hydrogen multienergy supply system[J]. Applied Energy, 2023, 348:121512.

OLIVIER P, BOURASSEAU C, BOUAMAMA PR B.Low-temperature electrolysis system modelling:a review[J]. Renewable and Sustainable Energy Reviews,2017, 78:280-300.

MARANGIO F, SANTARELLI M, CALI M. Theoretical model and experimental analysis of a high pressure PEM water electrolyser for hydrogen production[J].International Journal of Hydrogen Energy, 2009, 34(3):1143-1158.

KAYA M F, DEMIR N. Numerical investigation of PEM water electrolysis performance for different oxygen evolution electrocatalysts[J]. Fuel Cells, 2017, 17(1):37-47.

LISO V, SAVOIA G, ARAYA S S, et al. Modelling and experimental analysis of a polymer electrolyte membrane water electrolysis cell at different operating temperatures[J]. Energies, 2018, 11(12):3273.

GARCíA-VALVERDE R, ESPINOSA N, URBINA A.Simple PEM water electrolyser model and experimental validation[J]. International Journal of Hydrogen Energy,2012, 37(2):1927-1938.

CARMO M, FRITZ D L, MERGEL J, et al. A comprehensive review on PEM water electrolysis[J].International Journal of Hydrogen Energy, 2013, 38(12):4901-4934.

CORREA G, MAROCCO P, MU?OZ P, et al. Pressurized PEM water electrolysis:Dynamic modelling focusing on the cathode side[J]. International Journal of Hydrogen Energy, 2022, 47(7):4315-4327.

YIGIT T, SELAMET O F. Mathematical modeling and dynamic Simulink simulation of high-pressure PEM electrolyzer system[J]. International Journal of Hydrogen Energy, 2016, 41(32):13901-13914.

QI R, LI J, LIN J, et al. Thermal modeling and controller design of an alkaline electrolysis system under dynamic operating conditions[J]. Applied Energy, 2023, 332:120551.

ZHENG N, WANG Q, DING X, et al. Techno-economic analysis of a novel solar-based polygeneration system integrated with vanadium redox flow battery and thermal energy storage considering robust source-load response[J]. Applied Energy, 2024, 376:124288.

LIU P, SHU G, TIAN H, et al. Engine load effects on the energy and exergy performance of a medium cycle/organic rankine cycle for exhaust waste heat recovery[J]. Entropy, 2018, 20(2):137.

HARA N, TANIGUCHI S, YAMAKI T, et al. Impacts of hydrogen price and carbon dioxide emission factor on biobjective optimizations of absorption and subsequent methanation processes of carbon dioxide capture,utilization, and storage[J]. Journal of Cleaner Production,2024, 456:142358.

GE X, HE Y, LIANG X, et al. Thermally triggered polyrotaxane translational motion helps proton transfer[J].Nature Communications, 2018, 9(1):2297.

MIAO L, LIU M, ZHANG K, et al. Design and performance evaluation of thermal energy storage system with hybrid heat sources integrated within a coal-fired power plant[J]. Journal of Energy Storage, 2024, 82:110611.

BRIGUGLIO N, BRUNACCINI G, SIRACUSANO S, et al. Design and testing of a compact PEM electrolyzer system[J]. International Journal of Hydrogen Energy,2013, 38(26):11519-11529.

SAKAS G, IBá?EZ-RIOJA A, RUUSKANEN V, et al.Dynamic energy and mass balance model for an industrial alkaline water electrolyzer plant process[J]. International Journal of Hydrogen Energy, 2022, 47(7):4328-4345.

Views

106

下载量

CSCD

Alert me when the article has been cited

提交

Publicity Resources

Operation optimization of low-low temperature economizer combined air heater system

Application of two-stage double-cycle flue gas waste heat utilization system

可逆固体氧化物电池系统多变量参数优化及性能分析

Study on variable working condition and economy of regenerative heat storage peak regulation scheme for condensing units

Research progress on waste heat utilization technology in thermal power units

Related Author

LYU Kai

SHE Yuanyuan

ZHANG Zhixiang

WANG Dongye

YU Longwen

LIU Honggang

MA Tingshan

WANG Lin

Related Institution

Xi'an Xire Energy saving Technology Co., Ltd

Xi'an Thermal Power Research Institute Co., Ltd

华北电力大学能源电力创新研究院新型储能技术北京实验室

国网山东省电力公司电力科学研究院

中国电力科学研究院有限公司

⁰