电石渣混合碳化玉米纤维复合相变储热材料制备与性能研究

李萌; 熊亚选; 闫京; 尹美超; 苏娅楠; 吴玉庭; 丁玉龙

doi:10.19666/j.rlfd.202507130

English

您当前的位置：

首页 >

文章列表页 >

电石渣混合碳化玉米纤维复合相变储热材料制备与性能研究

Thermal Power Generation Vol. 55, Issue 2, Pages: 1-12(2026)

更新时间：2026-08-07

- 电石渣混合碳化玉米纤维复合相变储热材料制备与性能研究
- 作者机构：
  
  1. 北京建筑大学供热供燃气通风及空调工程北京市重点实验室
  2. 北京天岳恒房屋经营管理有限公司
  3. 北京工业大学传热与能源利用北京市重点实验室
  4. 伯明翰大学伯明翰储能中心
- 作者简介：
- 基金信息：
- DOI：10.19666/j.rlfd.202507130
  CLC： TB34
- Published：2026
- 稿件说明：
移动端阅览
[1]李萌,熊亚选,闫京,等.电石渣混合碳化玉米纤维复合相变储热材料制备与性能研究[J].热力发电,2026,55(02):1-12.
[1]李萌,熊亚选,闫京,等.电石渣混合碳化玉米纤维复合相变储热材料制备与性能研究[J].热力发电,2026,55(02):1-12. DOI： 10.19666/j.rlfd.202507130.

DOI：10.19666/j.rlfd.202507130.

摘要

【目的】为充分挖掘电石渣和玉米芯在资源化利用方面的巨大潜力，以满足固废资源化与低碳储能需求。【方法】以工业固废电石渣与农业固废碳化玉米纤维为二元骨架材料，石蜡为相变介质，采用真空浸渍工艺制备复合相变储热材料并优化工艺参数。【结果】结果发现：该材料在电石渣/碳化玉米纤维质量比5:5时封装性能最佳，经600次热循环后仍保持结构稳定；样品SC-5的熔融与凝固潜热可达34.90、36.35 J/g，导热系数0.484 W/(m·K)，表明其兼具良好的热稳定性与化学相容性；微观分析发现骨架材料形成致密多孔结构，可有效抑制石蜡渗漏；循环后的材料无新化学键生成，元素分布均匀。【结论】该研究为工农固废协同资源化提供了新路径，在建筑节能、工业余热回收及电子温控领域具有应用潜力。

Abstract

[Objective] To fully dig the enormous potential of carbide slag and corn cob in resource utilization

thus to meet the demands of colid waste recycling and low-carbon energy storage. [Methods] A novel composite phasechange thermal energy storage material was prepared using industrial solid waste carbide slag and agricultural solid waste carbonized corn fiber as the binary skeleton material

and with paraffin as the phase-change medium. The composites were synthesized via vacuum impregnation

and process parameters were optimized. [Results] The results showed that the material exhibited optimal encapsulation performance at a carbide slag-to-carbonized corn fiber mass ratio of 5:5

maintaining structural stability after 600 thermal cycles. The optimal sample SC-5 achieved melting and solidification latent heats of 34.90 and 36.35 J/g

respectively

with a thermal conductivity of 0.484 W/(m·K)

indicating good thermal stability and chemical compatibility. Microstructural analysis revealed that the skeleton materials formed a dense microporous structure

effectively mitigating paraffin leakage. Post-cycling material analysis indicated no new chemical bonds and maintained elemental homogeneity. [Conclusion] This work provides a novel pathway for synergistic valorization of industrial and agricultural solid wastes

demonstrating significant application potential in building energy conservation

industrial waste heat recovery

and thermal management of electronics.

关键词

Keywords

references

章姝,马堉博,郑馨竺,等.绿色低碳转型背景下能源安全评估体系重构与启示[J].中国工程科学, 2024,26(4):28-39.ZHANG Shu, MA Yubo, ZHENG Xinzhu, et al.Reconstruction and implications of energy security assessment system in the context of green and low-carbon transition[J]. Strategic Study of CAE, 2024, 26(4):28-39.

DING Y, ZHAO J, LIU J W, et al. A review of China’s municipal solid waste(MSW)and comparison with international regions:management and technologies in treatment and resource utilization[J]. Journal of Cleaner Production, 2021, 293:126144.

李飞,王福宁,金涛,等.大宗煤基固废利用研究现状与展望[J].山东化工, 2025, 54(1):75-78.LI Fei, WANG Funing, JIN Tao, et al. Research status and prospect on utilization of bulk coal-based solid waste[J].Shandong Chemical Industry, 2025, 54(1):75-78.

叶锦明,张伟杰,陈伟锦.大宗工业固体废物资源化利用处置研究——以钢铁行业为例[J].生态与资源,2025(2):84-86.YE Jinming, ZHANG Weijie, CHEN Weijin. Research on the resource utilization and disposal of bulk industrial solid waste:taking the steel industry as an example[J].Ecology and Resources, 2025(2):84-86.

黄喆,于志明,卿召进,等.旋转热边界下球形蓄热单元内PW/SEBS/EG复合相变材料的传热特性[J].储能科学与技术, 2025, 14(4):1413-1423.HUANG Zhe, YU Zhiming, QING Zhaojin, et al. Heat transfer characteristics of spherical thermal storage units based on PW/SEBS/EG composite phase change materials in a rotating fluid medium[J]. Energy Storage Science and Technology, 2025, 14(4):1413-1423.

刘伟,李振明,刘铭扬,等.高温相变储热材料制备与应用研究进展[J].储能科学与技术, 2023, 12(2):398-430.LIU Wei, LI Zhenming, LIU Mingyang, et al. Review of high-temperature phase change heat storage material preparation and applications[J]. Energy Storage Science and Technology, 2023, 12(2):398-430.

张新宇,罗声豪,吴颖欣,等.复合相变材料用于锂离子电池热管理和热失控防护研究进展[J].储能科学与技术, 2025, 14(3):1040-1053.ZHANG Xinyu, LUO Shenghao, WU Yingxin, et al.Research progress of composite phase change materials for thermal management and thermal runaway protection of lithium-ion batteries[J]. Energy Storage Science and Technology, 2025, 14(3):1040-1053.

LIU S, YANG H. Composite of coal-series kaolinite and Capric-Lauric acid as form-stable phasechange material[J]. Energy Technology, 2014, 3(1):77-83.

SARI A. Fabrication and thermal characterization of kaolin-based composite phase change materials for latent heat storage in buildings[J]. Energy and Buildings, 2015,96:193-200.

倪明龙,乐小龙,陈振乾,等.新型有机脂肪酸复合相变储能材料及应用前景[J].电力科技与环保, 2025,41(3):477-487.NI Minglong, YUE Xiaolong, CHEN Zhenqian, et al.Novel organic fatty acid composite phase change energy storage materials and application prospects[J]. Electric Power Technology and Environmental Protection, 2025,41(3):477-487.

王琴,孙浩焱,王元元,等.石墨烯/正十八烷复合相变材料制备及导热性能研究[J].计量学报, 2025,46(4):511-517.WANG Qin, SUN Haoyan, WANG Yuanyuan, et al.Preparation and thermal conductivity of graphene/Noctadecane composite phase change materials[J]. Acta Metrologica Sinica, 2025, 46(4):511-517.

LIU P, ZHANG Z, GU X, et al. Fabrication of a novel shape-stabilized composite phase change material based on multivariate supporting materials by using typical solid wastes[J]. Construction and Building Materials, 2020,240:118156.

熊亚选,药晨华,宋超宇,等.低成本兰炭灰骨架定型相变储热材料的制备及性能研究[J].华电技术, 2021,43(7):62-67.XIONG Yaxuan, YAO Chenhua, SONG Chaoyu, et al.Preparation and properties of low-cost phase-change heat storage materials based on semi-coke ash[J]. Huadian Technology, 2021, 43(7):62-67.

药晨华,熊亚选,任静,等.硝酸钠/兰炭灰复合相变储热材料的制备及性能[J].复合材料学报, 2023,40(1):300-309.YAO Chenhua, XIONG Yaxuan, REN Jing, et al.Preparation and properties of sodium nitrate/semi-coke ash shape-stable phase change composite[J]. Acta Materiae Compositae Sinica, 2023, 40(1):300-309.

宋超宇,熊亚选,张金花,等.污泥焚烧炉渣基定型复合相变储热材料的制备和性能[J].化工学报, 2022,73(5):2279-2287.SONG Chaoyu, XIONG Yaxuan, ZHANG Jinhua, et al.Preparation and performance study of incinerated slag based shape-stable phase change composites[J]. CIESC Journal, 2022, 73(5):2279-2287.

王晓宇,李健,张伟屹,等.黄金尾矿/粉煤灰制备相变储能材料及其性能研究[J].矿产保护与利用, 2023,43(6):72-78.WANG Xiaoyu, LI Jian, ZHANG Weiyi, et al. Preparation and properties of phase change energy storage materials with gold tailings/fly ash[J]. Conservation and Utilization of Mineral Resources, 2023, 43(6):72-78.

闫贞玮,高建明,马舒佳,等.聚乙二醇/粉煤灰定形相变材料的制备与性能[J].功能材料, 2025, 56(1):1184-1192.YAN Zhenwei, GAO Jianming, MA Shujia, et al.Preparation and properties of polyethylene glycol/fly ash shaped composite phase change materials[J]. Journal of Functional Materials, 2025, 56(1):1184-1192.

张越,蒋达华,黄世林,等.粉煤灰基相变储热调湿材料的研究进展[J].应用化工, 2024, 53(10):2439-2443.ZHANG Yue, JIANG Dahua, HUANG Shilin, et al.Research progress of phase change materials for heat storage and humidity control based on fly ash[J]. Applied Chemical Industry, 2024, 53(10):2439-2443.

HANIF F, IMRAN M, ZHANG Y, et al. Form-stable phase change material with wood-based materials as support[J]. Polymers, 2023, 15(4):942.

ZHOU X M, LIU Y F. Study on the preparation of high adsorption activated carbon material and its application as phase change energy storage carrier material[J]. Journal of Thermal Analysis and Calorimetry, 2021, 147(15):8169-8176.

XIONG Y X, WANG H X, REN J, et al. Carbide slag recycling to fabricate shape-stable phase change composites for thermal energy storage[J]. Journal of Energy Storage, 2023, 60:106694.

YANG J, ZHANG Y, HE X, et al. Heat-cured cementbased composites with wet-grinded fly ash and carbide slag slurry:hydration, compressive strength and carbonation[J]. Construction and Building Materials,2021, 307:124916.

XIONG Y X, WANG H X, WU Y T, et al. Carbide slag based shape-stable phase change materials for waste recycling and thermal energy storage[J]. Journal of Energy Storage, 2022, 50:104256.

熊亚选,王辉祥,胡子亮,等.电石渣骨架定型相变材料储热性能研究[J].综合智慧能源, 2022, 44(4):71-75.XIONG Yaxuan, WANG Huixiang, HU Ziliang, et al.Study on heat storage performance of shape-stable carbide slag skeleton phase change material[J]. Integrated Intelligent Energy, 2022, 44(4):71-75.

LIU K, ZHAO H, YUAN Z, et al. Preparation and characterization of steel slag-based low, medium, and high-temperature composite phase change energy storage materials[J]. Journal of Energy Storage, 2023, 57:106309.

ZHAO Y, ZHANG K, WANG C, et al. Study on the hydration reaction and pore structure of ecologically recycled mortar with corn cob aggregates[J]. Cement and Concrete Composites, 2024, 149:105493.

ABOU-HADID A F, EL-BEHAIRY U A, ELMALIH M M, et al. Conversion of corn shell as biomass solid waste into carbon species for efficient decontamination of wastewater via heavy metals adsorption[J]. Biomass Conversion and Biorefinery, 2023, 14(14):16435-16449.

LI H, HU C, HE Y, et al. Emerging surface strategies for porous materials-based phase change composites[J].Matter, 2022, 5(10):3225-3259.

SUN M, WANG Q, DI H. A review of lignocellulosic biomass-based shape-stable composite phase change materials[J]. Journal of Energy Storage, 2023, 73:109114.

YUWITA P E, MAS’UDAH K W, SUNARYONO, et al.Investigation of carbon phase structure of corncob charcoal powder[C]//Proceedings of the 3rd International Seminar on Metallurgy and Materials(ISMM2019):Exploring New Innovation in Metallurgy and Materials.2020.

王辉祥,熊亚选,任静,等. Na2CO3/电石渣复合相变储热材料制备与性能[J].储能科学与技术, 2022,11(12):3819-3827.WANG Huixiang, XIONG Yaxuan, REN Jing, et al.Fabrication and performance investigation of Na2CO3/carbide slag shape-stable phase change composites[J].Energy Storage Science and Technology, 2022, 11(12):3819-3827.

XIONG Y X, SUN M Y, WU Y T, et al. Effects of synthesis methods on thermal performance of nitrate salt nanofluids for concentrating solar power[J]. Energy&Fuels, 2020, 34(9):11606-11619.

田云峰,李珍,王洋,等.石蜡/不同粒径膨胀石墨复合相变储热材料的制备和性能[J].材料研究学报,2015, 29(4):262-268.TIAN Yunfeng, LI Zhen, WANG Yang, et al. Preparation and performance of a phase change heat storage composite of paraffin/different particle sized expanded graphite[J].Chinese Journal of Materials Research, 2015, 29(4):262-268.

PIELICHOWSKA K, PIELICHOWSKI K. Phase change materials for thermal energy storage[J]. Progress in Materials Science, 2014, 65:67-123.

WANG J, XIE H, GUO Z, et al. Improved thermal properties of paraffin wax by the addition of TiO2nanoparticles[J]. Applied Thermal Engineering, 2014,73(2):1541-1547.

JOGHATAEI M, OSTOVARI F, ATABAKHSH S, et al.Heterogeneous ice nucleation by graphene nanoparticles[J]. Scientific Reports, 2020, 10(1):9723.

汪向磊,郭全贵,王立勇,等.高导热定形聚乙烯/石蜡/膨胀石墨相变复合材料的研究[J].功能材料, 2013,44(23):3401-3404.WANG Xianglei, GUO Quangui, WANG Liyong, et al.Thermal conductivity enhancement of form-stable HDPE/paraffin by expanded graphite addition[J]. Journal of Functional Materials, 2013, 44(23):3401-3404.

ZHANG F, ZHANG H, SU Z. Surface treatment of magnesium hydroxide to improve its dispersion in organic phase by the ultrasonic technique[J]. Applied Surface Science, 2007, 253(18):7393-7397.

ZHAO Y, ZHANG X, XU X, et al. Research progress in nucleation and supercooling induced by phase change materials[J]. Journal of Energy Storage, 2020, 27:101156.

XIONG Y X, SONG C Y, REN J, et al. Sludge-incinerated ash based shape-stable phase change composites for heavy metal fixation and building thermal energy storage[J].Process Safety and Environmental Protection, 2022, 162:346-356.

ZOU H, FENG Y, QIU L, et al. Thermal conductance control of non-bonded interaction between loaded halogen molecules and carbon nanotubes:a molecular dynamics study[J]. International Journal of Heat and Mass Transfer,2022, 183:122216.

ZHAO M, PAN W, WAN C, et al. Defect engineering in development of low thermal conductivity materials:a review[J]. Journal of the European Ceramic Society, 2017,37(1):1-13.

ZHOU W X, CHENG Y, CHEN K Q, et al. Thermal Conductivity of Amorphous Materials[J]. Advanced Functional Materials, 2019, 30(8):1903829.

XIONG Y X, LI S, REN J, et al. Effect of ratio of desulfurization gypsum to carbide slag on low-carbon phase change composites for energy storage[J]. Journal of Energy Storage, 2024, 91:112086.

NIETO J T. Feature based costing of extruded parts[D].Chicago:University of Illinois, 2010:12-19.

JIANG Z, NAVARRO RIVERO M E, LIU X, et al. A novel composite phase change material for medium temperature thermal energy storage manufactured with a scalable continuous hot-melt extrusion method[J].Applied Energy, 2021, 303:117591.

BIANCO V, DE ROSA M, VAFAI K. Phase-change materials for thermal management of electronic devices[J]. Applied Thermal Engineering, 2022, 214:118839.

Views

337

下载量

CSCD

Alert me when the article has been cited

提交

Publicity Resources

Experimental research on COD treatment for carbide slag-gypsum flue gas desulfurization wastewater

基于知识图谱和检索增强生成的电站设备故障知识问答

电化学储能电站与新能源发电耦合系统设计、评价及规划配置研究综述

相变材料储热系统对火电机组抽汽调峰性能的影响

掺氢燃烧对SGT800燃气轮机联合循环机组热力性能影响的仿真研究

Related Author

WANG Meixia

XU Hongjian

XUE Yajing

CHANG Jiatao

CHEN Kuan

PAN Weiguo

Related Institution

School of Environmental and Chemical Engineering, Shanghai Electric Power University

Shanghai Power Generation Environmental Protection Engineering Technology Research Center

AI问答

⁰