核电厂锡黄铜冷却盘管泄漏原因分析及改进措施

毛彩云; 吴军轶; 韩玉刚; 张兴田

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核电厂锡黄铜冷却盘管泄漏原因分析及改进措施

热力发电 2013年42卷第5期页码：72-75

发电技术论坛 | 更新时间：2025-09-28

- 核电厂锡黄铜冷却盘管泄漏原因分析及改进措施
- Tin brass cooling plate tube leakage in a nuclear power plant:reason analysis and countermeasures
- 作者机构：
  
  中核核电运行管理有限公司二厂
- 作者简介：
- 基金信息：
- DOI：
  中图分类号： TM623
- 纸质出版：2013
- 稿件说明：
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毛彩云, 吴军轶, 韩玉刚, 等. 核电厂锡黄铜冷却盘管泄漏原因分析及改进措施[J]. 热力发电, 2013,42(5):72-75.

MAO Caiyun, Wu Junyi, HAN Yugang, et al. Tin brass cooling plate tube leakage in a nuclear power plant:reason analysis and countermeasures[J]. Thermal Power Generation, 2013, 42(5): 72-75.
毛彩云, 吴军轶, 韩玉刚, 等. 核电厂锡黄铜冷却盘管泄漏原因分析及改进措施[J]. 热力发电, 2013,42(5):72-75. DOI：

MAO Caiyun, Wu Junyi, HAN Yugang, et al. Tin brass cooling plate tube leakage in a nuclear power plant:reason analysis and countermeasures[J]. Thermal Power Generation, 2013, 42(5): 72-75. DOI：

摘要

针对某核电厂核岛应急通风系统的锡黄铜冷却盘管发生的泄漏事故

对泄漏管样进行了宏观检查、材质、腐蚀产物、电化学、裂纹宏微观和断口SEM形貌等分析。结果表明

冷却介质中亚硝酸盐环境下锡黄铜发生的应力腐蚀开裂(SCC)是导致其冷却盘管泄漏的主要原因。一方面是因为亚硝酸盐生成的NH4+使锡黄铜管对SCC特别敏感

另一方面锡黄铜管内的残余应力加剧了管的应力腐蚀倾向。对此

提出了将破损冷却盘管更换为紫铜管

并将缓蚀剂中TTA的含量由1.0mg/kg提高到10～20mg/kg等改进措施。

Abstract

Leakage occurred on tin brass cooling plate tubes of emergency ventilation system in a nuclear power plant.Thus

several investigations were carried out

such as the macroscopic examination

broken tube material analysis

corrosion product analysis

electrochemical analysis

macro and micro analysis of crack and fracture

and the fracture SEM analysis.The results showed that

stress corrosion cracking(SCC) occurred on the tin brass in nitrite environment in the cooling medium was considered as the major reason.One of the reason is the NH4+ formed by nitrite made the tin brass tube particularly sensitive to the SCC.On the other hand

residual stress on the tin brass tube exacerbated the stress corrosion tendency.Several measurements were put forward

like replacing the broken cooling plate tubes for red copper tubes

increasing the TTA content in corrosion inhibitor from 1.0 mg/kg to 10-20 mg/kg

and so on.

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