钾及其化合物对黑液水煤浆催化气化的作用

周志军; 林妙; 匡建平; 刘建忠; 周俊虎; 岑可法

doi:10.19666/j.rlfd.2006.10.020

English

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钾及其化合物对黑液水煤浆催化气化的作用

热力发电 2006年第10期页码：60-64

更新时间：2025-09-28

- 钾及其化合物对黑液水煤浆催化气化的作用
- EFFET OF POTASSIUM AND IT'S COMPOUND ON CATALYTIC GASSIFICATION OF COAL-BLACK LIQUOR SLURRY
- 作者机构：
  
  1. 浙江大学
  2. 1:浙江大学
  3. 2:浙江大学
  4. 3:浙江大学
  5. 4:浙江大学
- 作者简介：
- 基金信息：
  
  国家重点基础研究发展计划973计划资助项目(2004CB217701)
- DOI：10.19666/j.rlfd.2006.10.020
  中图分类号： X793
- 纸质出版：2006
- 稿件说明：
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周志军, 林妙, 匡建平, 等. 钾及其化合物对黑液水煤浆催化气化的作用[J]. 热力发电, 2006,(10):60-64.

EFFET OF POTASSIUM AND IT'S COMPOUND ON CATALYTIC GASSIFICATION OF COAL-BLACK LIQUOR SLURRY[J]. Thermal Power Generation, 2006, (10): 60-64.
周志军, 林妙, 匡建平, 等. 钾及其化合物对黑液水煤浆催化气化的作用[J]. 热力发电, 2006,(10):60-64. DOI： 10.19666/j.rlfd.2006.10.020.

EFFET OF POTASSIUM AND IT'S COMPOUND ON CATALYTIC GASSIFICATION OF COAL-BLACK LIQUOR SLURRY[J]. Thermal Power Generation, 2006, (10): 60-64. DOI： 10.19666/j.rlfd.2006.10.020.

摘要

对黑液水煤浆(由造纸黑液(废液)和煤制成)、水煤浆进行了等温和不等温热重试验

发现在1 200℃下

黑液水煤浆焦的转化率较高

气化活性比水煤浆焦提高了68.8%;黑液水煤浆焦的霞石衍射峰值比水煤浆焦高出22.5%;通过计算得到黑液水煤浆焦的活化能为125.44 kJ/mol

反应级数约为0.5

添加催化剂碳酸钾后煤焦的活化能比没有添加的下降了近40%。

Abstract

The thermogravimetric test under constant temperature and non-constant temperature has been carried out for coal-black liquor slurry which is made up from waste water of paper mills and coal

and for the ordinary coal-water slurry.It is discovered that the conversion rate of coal-black liquor slurry is higher under temperature of 1200 ℃

the gassifying activity had enhanced 68.6% from that of the ordinary coal-water slurry.The nephelite diffraction peak value of coal-black liquor slurry was 22.5% higher than that of ordinary coal-water slurry.Through calculation

it is obtaned that activation energy of coal-black liquor slurry coke is 125.44 kJ/mol

reactive degree is about 0.5

after adding catalyst potassium carbonate

the activation energy of coal coke has decreased near 4% from that without adding catalyst.

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