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1. 中国石油大学(北京)非常规油气科学技术研究院
2. 中国石油大学(北京)温室气体封存与石油开采利用北京市重点实验室
3. 中国建筑材料科学研究总院绿色建筑材料国家重点实验室
网络出版:2020-12-30,
纸质出版:2021
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李林坤, 刘琦, 马忠诚, 等. 二氧化碳矿化强化混凝土再生骨料性能研究进展[J]. 热力发电, 2021,50(1):94-103.
LI Linkun, LIU Qi, MA Zhongcheng, et al. Research progress on properties of recycled concrete aggregates by carbon dioxide mineral carbonation curing[J]. Thermal Power Generation, 2021, 50(1): 94-103.
李林坤, 刘琦, 马忠诚, 等. 二氧化碳矿化强化混凝土再生骨料性能研究进展[J]. 热力发电, 2021,50(1):94-103. DOI: 10.19666/j.rlfd.202007191.
LI Linkun, LIU Qi, MA Zhongcheng, et al. Research progress on properties of recycled concrete aggregates by carbon dioxide mineral carbonation curing[J]. Thermal Power Generation, 2021, 50(1): 94-103. DOI: 10.19666/j.rlfd.202007191.
碳捕集、利用与封存(CCUS)作为大规模碳减排的有效路径之一
对全球应对气候变化意义重大。在现有的CCUS技术中
CO_2矿化封存技术是利用自然界或工业生产中含钙、镁的碱土金属离子矿物将CO_2矿化处理形成热稳定较高的无机碳酸盐的技术。该技术在减少CO_2排放的同时
实现了高性能建筑材料的生产和固体废弃物的资源化利用
是附带显著经济效益的CO_2减排途径。CO_2矿化强化混凝土再生骨料是基于CO_2矿化封存技术
利用CO_2与废弃混凝土经破碎筛分获得的再生骨料反应
制得高性能的再生骨料。在反应过程中
骨料表面附着的砂浆中含有的氢氧化钙和水化硅酸钙凝胶与CO_2作用后形成碳酸钙和硅胶并填充于浆体孔隙中
使浆体整体微观结构更加致密
提高了骨料性能
可满足现阶段的工程应用需求。本文从CO_2矿化封存机理、影响矿化反应速率的因素、工艺路线等方面对CO_2矿化封存技术应用于再生骨料强化的进展进行论述
并对CO_2矿化强化再生骨料的未来发展进行了展望。
Carbon capture
utilization and storage(CCUS) has been identified as an important strategy to reduce CO_2 emissions and mitigate climate change. Mineral carbonation(MC) is emerging as a potential CCUS technology
in which calcium(Ca) or magnesium(Mg) from silicate minerals is bound with CO_2
forming benign and stable calcium/magnesium carbonates. Mineral carbonation not only reduces CO_2 emissions with relatively low overall cost
but also produces high-performance concrete with the use of solid waste. CO_2 curing is a mineral carbonation process where CO_2 is chemically reacted with calcium hydroxide and calcium silica hydrate in recycled concrete aggregate taken from construction and demolition(CD) waste
forming thermodynamically stable carbonate minerals to enhance the properties of the concrete aggregate. In this paper
the progress of using CO_2 mineralization and sequestration technology to improve recycled concrete aggregate is discussed in detail in the perspectives of reaction mechanisms
factors influencing reaction kinetics
and various process routes. Finally
based on a discussion of current research state and existing problems
future prospect of reinforced recycled concrete aggregate produced by CO_2 mineralization are summarized.
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