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1. 厦门华夏国际电力发展有限公司
2. 煤燃烧国家重点实验室(华中科技大学)
3. 西安热工研究院有限公司苏州分公司
4. 华能上海石洞口第二电厂
纸质出版:2022
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黄见勋, 尹子骏, 马云龙, 等. 燃煤烟气脱硝喷卤素协同脱汞效果评估[J]. 热力发电, 2022,51(10):194-200.
HUANG Jianxun, YIN Zijun, MA Yunlong, et al. Effect evaluation of synergistic mercury removal by halogen injection and gas denitrification in coal-fired power plant[J]. Thermal Power Generation, 2022, 51(10): 194-200.
黄见勋, 尹子骏, 马云龙, 等. 燃煤烟气脱硝喷卤素协同脱汞效果评估[J]. 热力发电, 2022,51(10):194-200. DOI: 10.19666/j.rlfd.202203038.
HUANG Jianxun, YIN Zijun, MA Yunlong, et al. Effect evaluation of synergistic mercury removal by halogen injection and gas denitrification in coal-fired power plant[J]. Thermal Power Generation, 2022, 51(10): 194-200. DOI: 10.19666/j.rlfd.202203038.
为进一步降低现有燃煤机组烟气污染物排放质量浓度,实现大气污染物的协同深度治理,选取现役的选择性催化还原(SCR)催化剂作为研究对象,对不同条件下HCl/HBr等卤素成分对现役SCR催化剂脱硝协同汞氧化效果进行实验研究,并设计卤素溶液喷射系统,依据实验室研究结果,在现场脱硝过程中进行了不同浓度NH_4Cl/NH_4Br溶液喷射的工程应用与试验。结果表明:脱硝过程合理添加NH_4Cl或NH_4Br溶液均可有效提高现役SCR脱硝催化剂对单质汞氧化能力,HCl/HBr共同作用可以提高单一HCl在SCR催化剂表面对单质汞的氧化效果,进一步通过脱硝、下游脱硫、除尘等环保设施实现汞污染物的高效协同脱除。
In order to further reduce the emission mass concentration of pollutants from flue gas of existing coalfired units and realize coordinated and deep treatment of air pollutants
the active selective catalytic reduction(SCR)catalyst was selected as the research object
and the influence mechanism of halogen components such as HCl/HBr on the denitration synergistic mercury oxidation performance of the SCR catalyst under different conditions was systematically studied. Moreover
the halogen solution injection system was designed. According to the research result in laboratory
the engineering application and test using NH_4Cl/NH_4Br solution injection were carried out in the field denitration process. The results show that
reasonable addition of NH_4Cl or NH_4Br solution during the denitration process can effectively improve the mercury oxidation capacity of the existing catalyst. The combined action of HCl/HBr can improve the oxidation effect of single HCl on elemental mercury on the catalyst surface.Furthermore
through the denitration
downstream desulfurization
dust removal and other environmental protection facilities
efficient synergistic removal of mercury pollutants can be realized.
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