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1. 中电建生态环境集团有限公司
2. 中国电建集团西北勘测设计研究院有限公司
3. 华北电力大学新能源发电国家工程研究中心
4. 中国电力工程顾问集团西南电力设计院有限公司
纸质出版:2024
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陈秋宇, 李文涛, 李竺豫, 等. 中高温热化学储热材料研究进展[J]. 热力发电, 2024,53(6):12-20.
CHEN Qiuyu, LI Wentao, LI Zhuyu, et al. Research progress on thermochemical heat storage materials for medium to high temperature applications[J]. Thermal Power Generation, 2024, 53(6): 12-20.
陈秋宇, 李文涛, 李竺豫, 等. 中高温热化学储热材料研究进展[J]. 热力发电, 2024,53(6):12-20. DOI: 10.19666/j.rlfd.202403033.
CHEN Qiuyu, LI Wentao, LI Zhuyu, et al. Research progress on thermochemical heat storage materials for medium to high temperature applications[J]. Thermal Power Generation, 2024, 53(6): 12-20. DOI: 10.19666/j.rlfd.202403033.
可再生能源在利用过程中存在瞬时性、不稳定性以及供应与需求不匹配等问题。热化学储热技术具有储能密度大、储热温度高等特点,能够实现高效长时储热,可以将不稳定的可再生能源转化为稳定的中高温热能,并满足用户侧的波动需求。针对工作温度范围为400~1 100℃的中高温热化学储热材料,阐述了其分类、基本原理和特点,系统总结了碳酸盐、氢氧化物、氧化物、金属氢化物、氨和甲烷等典型热化学储热材料及其储热性能,分析了其结构定向调控及改性方法,并对典型的工程应用进行了介绍;分析了固-气和气-气反应体系的反应器设计及系统集成的研究进展,并针对优质热化学储能材料在开发及工业应用方面存在的问题,指出了未来的发展方向。
Renewable energy suffers some drawbacks such as instantaneity
instability
and the mismatch between supply and demand during the utilization. Thermochemical heat storage exhibits distinct advantages
including high heat storage density
elevated heat storage temperature
and negligible heat loss during the long-term storage.It has the capability to convert intermittent energy sources into stable moderate and high temperature heat energy to fulfill the needs of fluctuating output. The classification
basic mechanisms and characteristics of thermochemical heat storage within reaction temperature range of 400~1 100 ℃ are reviewed. Subsequently
the thermal storage performance of typical thermochemical heat storage materials
such as carbonates
hydroxides
oxides
metal hydrides
ammonia and methane are analyzed
and the structural targeted regulation and modification methods are investigated
alongside the introduction of typical demonstration projects. Following this
the reactor design and system integration of solid-gas and gas-gas reaction systems are discussed. In the last
the future research interests are deliberated and proposed in the development and industrial application of thermochemical energy storage materials.
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