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合肥工业大学电气与自动化工程学院
纸质出版:2024
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侯谋, 郑涛, 贾泽峰, 等. 旁路电流对全钒液流电池库伦效率的影响[J]. 热力发电, 2024,53(12):57-67.
HOU Mou, ZHENG Tao, JIA Zefeng, et al. Effect of bypass current on coulombic efficiency of vanadium redox flow battery[J]. Thermal Power Generation, 2024, 53(12): 57-67.
侯谋, 郑涛, 贾泽峰, 等. 旁路电流对全钒液流电池库伦效率的影响[J]. 热力发电, 2024,53(12):57-67. DOI: 10.19666/j.rlfd.202405116.
HOU Mou, ZHENG Tao, JIA Zefeng, et al. Effect of bypass current on coulombic efficiency of vanadium redox flow battery[J]. Thermal Power Generation, 2024, 53(12): 57-67. DOI: 10.19666/j.rlfd.202405116.
为提高全钒液流电池(VRB)系统中电池的性能和效率,根据VRB的组成及原理,建立了包括电化学、流体力学、温度、旁路电流、钒电池多堆等效损耗电路模型,并探究全钒液流电池管道系统中的泵送损耗与旁路电流对钒电池的影响。通过建立泵送损耗和泵损电流之间关系、旁路电流模型、多堆串联的钒电池等效电路模型,将各模型“化零为整”,阐述了计及动态响应的钒电池的内核机理。详细探讨了VRB建模中涉及的关键因素,包括泵送损耗、旁路电流,并分析了电池性能和效率的影响因素。研究表明,管道的长度与横截面积等参数影响着管路电阻,较长的主管与支管会减小旁路电流,但会增大泵损电流;较长和较粗的管道有利于同时减小旁路电流和泵送损耗,提高了电池的能量效率,这为厂家管路设计提供了思路。
In order to improve the performance and efficiency of the battery in vanadium redox battery(VRB)system
a multi-stack equivalent loss circuit model is developed based on the composition and principles of VRBs
which includes electrochemical
hydrodynamic
temperature
bypass current
and vanadium batteries. Moreover
the effects of pumping loss and bypass current on vanadium batteries in the pipeline system of all-vanadium flow batteries are investigated. The relationship between pumping loss and pumping current
the bypass current model
and the equivalent circuit model of vanadium battery with multiple stacks connected in series are established
and the core mechanism of the vanadium battery taking into account the dynamic response is elaborated by transforming each model into a whole. The key factors involved in modelling of the VRB
including the pumping loss and bypass current
are discussed in detail. The influencing factors of battery performance and efficiency are also analyzed. The results show that
parameters such as the length and cross-sectional area of the pipeline affect the pipeline resistance
and the resistance of longer main and branch pipes will reduce the bypass current but increase the pumping loss current. Longer and thicker pipelines are conducive to the simultaneous reduction of both the bypass current and the pumping loss
which improves the energy efficiency of the battery. The research provides an idea for design of the manufacturer's pipeline.
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