集成合成氨余热储存利用质子交换膜电解槽制氢/热备双模式运行性能

裴长运; 孙名家; 王桂楠; 殷诗奇; 王露; 宋玮; 彭莘; 于吉庆; 杜逸云; 郭铁柱; 张汉飞

doi:10.19666/j.rlfd.202411252

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集成合成氨余热储存利用质子交换膜电解槽制氢/热备双模式运行性能

热力发电 2025年54卷第8期页码：84-94

绿氢绿氨多能协同优化 | 更新时间：2026-08-11

- 集成合成氨余热储存利用质子交换膜电解槽制氢/热备双模式运行性能
- Operation performance of PEM electrolyzer in dual-mode operation for hydrogen production and hot standby with integrated ammonia synthesis waste heat storage and utilization
- 作者机构：
  
  1. 国核电力规划设计研究院有限公司
  2. 华北电力大学能源动力与机械工程学院
  3. 吉林电力股份有限公司
  4. 大安吉电绿氢能源有限公司
- 作者简介：
- 基金信息：
  
  国家自然科学基金重大项目(52090064)~~
- DOI：10.19666/j.rlfd.202411252
  中图分类号： TQ113.2;TQ116.2
- 纸质出版：2025
- 稿件说明：
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[1]裴长运,孙名家,王桂楠,等.集成合成氨余热储存利用质子交换膜电解槽制氢/热备双模式运行性能[J],2025,54(08):84-94.
[1]裴长运,孙名家,王桂楠,等.集成合成氨余热储存利用质子交换膜电解槽制氢/热备双模式运行性能[J],2025,54(08):84-94. DOI： 10.19666/j.rlfd.202411252.

DOI：10.19666/j.rlfd.202411252.

摘要

绿电制氢合成氨是大规模消纳风光可再生电能并解决绿色燃料化学品短缺问题的有效方案。提出了一种集成合成氨余热储存利用的风光驱动质子交换膜电解槽制氢/热备双模式运行系统，避免电解槽频繁启停并合理解决合成氨工艺余热浪费问题。结果表明：双模式运行系统可大幅降低电解槽启动时间，951 kW电解槽25℃冷启动耗时512 s，从热备模式47.5℃热启动仅需274 s；系统在热备模式下仅给水泵耗电，单位制氢容量耗电功率为0.49 kW；双罐储热子系统配置10.8 t Dowtherm-G导热油，在蓄热状态以3 kg/s的流量吸收合成氨装置余热气体，可使热罐1.00 h内储满，在放热状态以0.64 kg/s的流量加热电解槽入口给水，可使电解槽热备状态持续运行4.68 h。此外，通过制氢/热备双模式运行产生的收益超出储热子系统投资，具有良好的经济性。

Abstract

Ammonia synthesize through hydrogen produced by green electricity offers an effective solution to the widespread abandonment of wind and solar resources and the shortage of green fuel chemicals. A wind-solar-driven proton exchange membrane(PEM) electrolyzer system in dual-mode operation for hydrogen production and hot standby with integrated ammonia synthesis waste heat storage is proposed

addressing issues of frequent start-stop cycles under fluctuating wind-solar outputs and waste heat recovery in ammonia synthesis processes. The results indicate that

the PEM electrolyzer dual-mode operating system

integrated with ammonia synthesis waste heat storage

can significantly shorten the startup time of the electrolyzer. The startup time at 25 ℃ is 512 seconds

while the hot startup from the standby mode at 47.5 ℃ requires only 274 seconds. Under hot standby mode

the system consumes electricity solely from feedwater pumps

achieving a specific hydrogen production power consumption of only 0.49 kW. The dual-tank thermal storage subsystem is configured with 10.8 tons of Dowtherm-G heat transfer oil. In heat storage mode

it absorbs waste heat gas from the ammonia synthesis unit at a flow rate of 3 kg/s

allowing the thermal tank to reach full capacity within 1 hour. In heat release mode

it heats the electrolyzer inlet water at a flow rate of 0.64 kg/s

enabling the electrolyzer to sustain standby operation for 4.68 hours. Furthermore

the new system is expected to generate long-term benefits that consistently exceed costs

ensuring sustained economic viability.

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