磷酸酯抗燃油成分分析及性能研究

高占阳; 王笑微; 张帆; 王娟; 崔锐; 龙国军; 王宇; 徐勇智; 王伦; 韩明睿; 刘杰

doi:10.19666/j.rlfd.202503067

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磷酸酯抗燃油成分分析及性能研究

热力发电 2026年55卷第3期页码：64-71

热能科学研究 | 更新时间：2026-08-07

- 磷酸酯抗燃油成分分析及性能研究
- 磷酸酯抗燃油成分分析及性能研究
- 作者机构：
  
  1. 西安热工研究院有限公司
  2. 华能甘肃能源开发有限公司西固分公司
- 作者简介：
- 基金信息：
  
  中国华能集团有限公司总部科技项目（HNKJ23-H22）~~
- DOI：10.19666/j.rlfd.202503067
  中图分类号： TM621
- 纸质出版：2026
- 稿件说明：
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[1]高占阳,王笑微,张帆,等.磷酸酯抗燃油成分分析及性能研究[J].热力发电,2026,55(03):64-71.
[1]高占阳,王笑微,张帆,等.磷酸酯抗燃油成分分析及性能研究[J].热力发电,2026,55(03):64-71. DOI： 10.19666/j.rlfd.202503067.

DOI：10.19666/j.rlfd.202503067.

摘要

磷酸酯抗燃油作为电厂汽轮机调速系统的工作介质，对汽轮机的正常运转起着至关重要的作用。运行中因油质劣化可能出现油质酸值升高，体积电阻率下降，以及生成油泥的情况，不同油品分解劣化程度不一致。对不同种类磷酸酯抗燃油化学成分进行分析，模拟不同磷酸酯分子劣化过程，并检测其抗老化性能。结果表明：以三-（二甲基苯基）磷酸酯为主要组分的磷酸酯抗燃油稳定性能优于以叔丁基苯基磷酸酯为主要组分的磷酸酯抗燃油；在研制磷酸酯抗燃油过程中，应提高三芳基磷酸酯中二甲基苯基的含量，降低苯基和叔丁基苯基的含量。

Abstract

As the working medium of turbine speed-control systems in power plants

phosphate ester fire-resistant fluid(FRF) plays a vital role in the normal operation of steam turbines. During operation

the deterioration of FRF may result in an increase in acid value

a decrease in volume resistivity

and the formation of oil sludge

and the degree of decomposition and deterioration varies among different oils. The chemical composition of different kinds of FRF samples was analyzed

the deterioration process of different phosphate ester molecules was simulated

and their aging-resistance properties were tested. The results show that the performance of FRF with tris-(dimethylphenyl) phosphate as the main component is more stable than that of FRF with tert-butylphenyl phosphate as the main component. During the production of FRF

the content of dimethylphenyl in triaryl phosphate should be increased

and the content of phenyl and tert-butyl phenyl should be reduced.

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Keywords

references

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