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中国石油大学(北京)重质油国家重点实验室
纸质出版:2026
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杨云杰, 陈哲文, 魏俊杰, 等. 天然气SOFC耦合热泵热电联产系统的热力学分析[J]. 热力发电, 2026,(6).
杨云杰, 陈哲文, 魏俊杰, et al. 天然气SOFC耦合热泵热电联产系统的热力学分析[J]. Thermal Power Generation, 2026, (6).
杨云杰, 陈哲文, 魏俊杰, 等. 天然气SOFC耦合热泵热电联产系统的热力学分析[J]. 热力发电, 2026,(6). DOI: 10.19666/j.rlfd.202508027.
杨云杰, 陈哲文, 魏俊杰, et al. 天然气SOFC耦合热泵热电联产系统的热力学分析[J]. Thermal Power Generation, 2026, (6). DOI: 10.19666/j.rlfd.202508027.
【目的】为提升热电联产系统的能源利用效率与综合性能,解决传统系统热效率与(火用)效率较低的问题,提出一种耦合固体氧化物燃料电池(SOFC)与溴化锂吸收式热泵的新型热电联产系统。【方法】首先,构建了系统的热力学与经济性分析模型。该系统利用SOFC进行富氧燃烧,产生的高温烟气依次用于空气预热、甲烷预热、水预热及蒸汽制备,并将所制蒸汽驱动溴化锂吸收式热泵以实现供热;随后,采用参数敏感性分析方法,系统探究了水碳比、SOFC工作温度及燃料利用率3个关键参数对系统性能的影响规律。【结果】研究表明:随着水碳比增加,SOFC发电效率与系统热效率呈下降趋势,而热泵性能系数(COP)稳定在1.72左右;随着工作温度升高,发电效率与系统热效率均显著提升;随着燃料利用率提高,发电效率增大,但系统热效率有所降低。在水碳比为2、工作温度1 000℃、燃料利用率0.85的优化工况下,系统发电效率达52%,(火用)效率为56.6%,热效率达100.54%。相较于参比系统,该系统热效率提升了20%,(火用)效率提升2.6%,有效能平准化成本为0.102 6美元/(kW·h),动态投资回收期为8年。【结论】该耦合系统通过优化能量梯级利用模式,显著提升了能源利用效率与综合性能,具备良好的经济性与工程应用潜力。研究揭示的关键参数影响机制可为系统优化设计与运行调控提供理论依据。
[Objective] Conventional combined heating and power(CHP) systems often suffer from suboptimal thermal integration and limited exergy utilization
resulting in low overall energy efficiency and significant carbon emissions. To address these challenges
this study proposes a novel high-efficiency CHP system based on the synergistic integration of a solid oxide fuel cell(SOFC) and a lithium bromide(LiBr) absorption heat pump. The architecture is specifically designed to maximize cascaded energy recovery and enhance comprehensive thermodynamic and economic performance. [Methods] A comprehensive steady-state model encompassing thermodynamic and economic analysis was developed to evaluate the system behavior. In the proposed configuration
unreacted fuel in the SOFC anode exhaust is combusted using oxy-fuel technology
yielding a CO2-concentrated flue gas suitable for carbon capture while simultaneously upgrading waste heat quality. The hightemperature flue gas is then recovered through an advanced cascaded heat exchanger network
sequentially enabling cathode air preheating
endothermic methane reforming
and high-pressure steam generation. This steam serves as the thermal driving source for the Li Br absorption heat pump to meet heating demands. A detailed parametric sensitivity analysis was conducted to investigate the effects of the steam-to-carbon ratio
SOFC operating temperature
and fuel utilization factor on key performance indicators. [Results] Simulation results show that increasing the steam-to-carbon ratio monotonically reduces both SOFC electrical efficiency and overall thermal energy utilization efficiency
whereas the coefficient of performance(COP) of the absorption heat pump remains stable at approximately 1.72. Higher SOFC operating temperatures significantly improve electrochemical kinetics and flue gas quality
thereby enhancing both electrical and thermal performance. A clear trade-off is observed with fuel utilization: higher fuel utilization factor increases electrical output but diminishes the availability of high-grade heat for downstream recovery. Under optimized conditions(with the steam-to-carbon ratio of 2
temperature of 1 000 ℃
and fuel utilization ratio of 0.85)
the system achieves an electrical efficiency of 52%
an exergy efficiency of 56.6%
and an overall thermal energy utilization efficiency of 100.54%(defined on the basis of the fuel's lower heating value
including all recovered thermal energy). Compared to a conventional natural gas-fired CHP benchmark
the proposed system improves the thermal utilization efficiency by 20%
and increases the exergy efficiency by 2.6%. Economic evaluation yields a levelized cost of exergy of 0.102 6 dollars/(kW·h) and a dynamic payback period of 8 years under current industrial energy pricing. [Conclusion] This coupled system significantly improves the energy utilization efficiency and comprehensive performance through the optimization of the energy cascade utilization mode. It demonstrates substantial economic feasibility and potential for engineering applications. The identified influence mechanisms of key parameters provide a theoretical foundation for the optimal design and operational control of such systems.
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