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1. 国源电力(神东电力)公司技术支持中心
2. 西安交通大学能源与动力工程学院
纸质出版:2026
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吴锡鹏, 周定文, 赵勇纲, 等. 低负荷工况高碱煤燃烧沾污与NOx生成特性实验研究[J]. 热力发电, 2026,(10). DOI: 10.19666/j.rlfd.202602027.
吴锡鹏, 周定文, 赵勇纲, et al. 低负荷工况高碱煤燃烧沾污与NOx生成特性实验研究[J]. Thermal Power Generation, 2026, (10). DOI: 10.19666/j.rlfd.202602027.
【目的】高碱煤燃用极易引发严重的沾污结渣问题。当前已有的研究多集中于常规负荷,在锅炉深度调峰降至低负荷后,高碱煤燃烧沾污与NO
x
生成特性的机理变化尚不明晰,需进一步深入研究。【方法】利用马弗炉与两段沉降炉,对低负荷高碱煤燃烧沾污与NO
x
生成特性开展针对性的实验。【结果】实验结果表明:哈密煤随埋藏深度变深,灰分中碱金属赋存形式由硅铝酸盐逐渐向硫酸盐转变。相比常规负荷,在深度调峰低负荷下,铁、硫、钙含量高的高碱煤由于灰分表面钠与硫酸钙等颗粒数量增加,灰分黏性增大,沾污倾向增大;硅、铝含量高的高碱煤由于游离钠多数被硅或铝捕获,且钙的释放被抑制,灰分表面黏性颗粒数量变化不大,沾污倾向变化较小,甚至可能降低。同时,深度调峰低负荷下,高碱煤燃烧的氮转化率普遍升高约7%,但有较高挥发分(30%)煤种的氮转化率可能降低。【结论】当锅炉由常规负荷转为深度调峰低负荷运行时,可优先选取有较高挥发分且硅、铝含量较高煤种燃用,保障机组运行的安全性。
[Objective
]
The combustion of high-alkali coal is highly susceptible to severe fouling and slagging issues. Existing research has primarily focused on conventional loads. However
after the boiler drops to low load under deep peak shaving
the mechanisms underlying changes in fouling and NO
x
generation characteristics during highalkali coal combustion remain unclear
necessitating further in-depth investigation. [Methods
]
Targeted experiments were conducted using a muffle furnace and a two-stage drop tube furnace to study the fouling and NO
x
generation characteristics of high-alkali coal combustion under low-load conditions. In the two-stage drop tube furnace experiments
both conventional load and low load conditions were set to simulate actual deep peak-shaving scenarios. [Results
]
The experimental results indicate
that for Hami coal
as the burial depth increases
the occurrence forms of alkali metals in the ash gradually shift from aluminosilicates to sulfates. Moreover
the degree of influence of load variations on the microscopic morphology of ash also diminishes. Compared to conventional loads
under deep peak-shaving low loads
high-alkali coal with high iron
sulfur
and calcium content exhibits enhanced ash melting
increased viscosity
and a greater propensity for fouling(from 14.6 to 16.2 mg/g and from 9.0 to 12.8 mg/g) due to an increase in particles such as sodium and calcium sulfate on the ash surface. In contrast
high-alkali coal with high silicon and aluminum content shows little change in the number of sticky particles on the ash surface
resulting in a smaller or even reduced propensity for fouling(from 12.9 to 6.7 mg/g)
as most of the free sodium is captured by silicon or aluminum
and the release of calcium is suppressed. Furthermore
under deep peak-shaving low loads
the nitrogen conversion rate of high-alkali coal combustion generally increases by approximately 7%. However
for coal types with higher volatile matter content(30%)
the nitrogen conversion rate could decrease. This could be attributed to the organic volatiles released during combustion
which are difficult to fully burn at lower temperatures
leading to a significant decline in combustion efficiency. [Conclusion
]
When a boiler shifts from conventional load operation to deep peak-shaving under low-load conditions
priority should be given to selecting coal types with higher volatile matter content and higher levels of silicon and aluminum to ensure the safety and reliability of unit operation.
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